Tris(ethylenediamine)zinc(II) hexafluoridosilicate
نویسندگان
چکیده
The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa-hedral geometry. The Zn(II) ion is coordinated by six N atoms from three ethyl-enediamine mol-ecules. The crystal structure displays weak hydrogen bonding between [SiF(6)](2-) anions and the ethyl-enediamine NH hydrogen atoms.
منابع مشابه
Tris(ethylenediamine)zinc(II) dichloride monohydrate
The asymmetric unit of the title compound, [Zn(C(2)H(8)N(2))(3)]Cl(2)·H(2)O, contains a discrete [Zn(C(2)H(8)N(2))(3)](2+) cation with a distorted octa-hedral geometry around Zn, two uncoordinated chloride ions and one water mol-ecule. The crystal structure exhibits N-H⋯O, N-H⋯Cl and O-H⋯O hydrogen bonds.
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متن کاملTris(ethylenediamine)nickel(II) 1H-pyrazole-3,5-dicarboxylate 1.67-hydrate
The asymmetric unit of the title compound, [Ni(C(2)H(8)N(2))(3)](C(5)H(2)N(2)O(4))·1.67H(2)O, consists of three [Ni(en)(3)](2+) dications (en is ethyl-enediamine), three [(pzdc)(3)](2-) dianions (pzdc is pyrazole-3,5-dicarboxyl-ate) and five water mol-ecules. In each complex dication, the Ni(II) atom is coordinated by six N atoms from three en ligands forming a distorted octa-hedral coordinatio...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009